Spatiotemporal distribution, source analysis and ecological risk assessment of polychlorinated biphenyls (PCBs) in the Bohai Bay, China.

As a class of persistent organic pollutants (POPs), the spatial and temporal distribution of polychlorinated biphenyls (PCBs) in seawater is important for environmental assessment. Surface water samples were collected from 35 stations during summer and 36 stations during autumn of 2020 in the Bohai Bay. The concentration, composition, distribution and sources of PCBs were analyzed to assess the ecological impact of PCBs. The average concentration of ∑18PCBs was 124.6 ng/L (range of 28.1-445.5 ng/L) in summer and 122.8 ng/L (range of 21.0-581.4 ng/L) in autumn. PCBs in surface seawater of the Bohai Bay showed high near-shore and low far-shore characteristics, indicating the serious influence of land-based sources such as port activities and river inputs. Proportion analysis showed that Tetra-PCBs and Penta-PCBs were the major constituents in most stations. It was assessed as moderate and high risk (MRQ > 0.1) by mixture risk quotient (MRQ) and concentration addition (CA) model in surface seawater of the Bohai Bay. Principal component analysis (PCA) was used to explain the sources of PCBs in the Bohai Bay. PCBs in the Bohai Bay may come from commercial PCBs and their incineration products, municipal landfills, wood and coal combustion, and industrial activities, etc.

Seasonal variation and ecological risk assessment of Pharmaceuticals and Personal Care Products (PPCPs) in a typical semi-enclosed bay - The Bohai Bay in northern China.

The Bohai Bay as a typical semi-enclosed bay in northern China with poor water exchange capacity and significant coastal urbanization, is greatly influenced by land-based inputs and human activities. As a class of pseudo-persistent organic pollutants, the spatial and temporal distribution of Pharmaceuticals and Personal Care Products (PPCPs) is particularly important to the ecological environment, and it will be imperfect to assess the ecological risk of PPCPs for the lack of systematic investigation of their distribution in different season. 14 typical PPCPs were selected to analyze the spatial and temporal distribution in the Bohai Bay by combining online solid-phase extraction (SPE) and HPLC-MS/MS techniques in this study, and their ecological risks to aquatic organisms were assessed by risk quotients (RQs) and concentration addition (CA) model. It was found that PPCPs widely presented in the Bohai Bay with significant differences of spatial and seasonal distribution. The concentrations of ∑PPCPs were higher in autumn than in summer. The distribution of individual pollutants also showed significant seasonal differences. The high values were mainly distributed in estuaries and near-shore outfalls. Mariculture activities in the northern part of the Bohai Bay made a greater contribution to the input of PPCPs. Caffeine, florfenicol, enrofloxacin and norfloxacin were the main pollutants in the Bohai Bay, with detection frequencies exceeding 80 %. The ecological risk of PPCPs to algae was significantly higher than that to invertebrates and fish. CA model indicated that the potential mixture risk of total PPCPs was not negligible, with 34 % and 88 % of stations having mixture risk in summer and autumn, respectively. The temporary stagnation of productive life caused by Covid-19 weakened the input of PPCPs to the Bohai Bay, reducing the cumulative effects of the pollutants. This study was the first full-coverage investigation of PPCPs in the Bohai Bay for different seasons, providing an important basis for the ecological risk assessment and pollution prevention of PPCPs in the bay.

Biodiversity assessment in the near-shore waters of Tianjin city, China based on the Pressure-State-Response (PSR) method.

Parameters regarding water quality, biology, marine disasters, and anthropogenic factors were collected and analyzed from 2020 to 2021 to evaluate the marine biodiversity of Tianjin's near-shore sea area accurately. A total of 29 indicators obtained from the surveys were selected to form the biodiversity evaluation system. The Pressure-State-Response (PSR) framework model combined with the ecological environment characteristics was used as the assessment method. The analytic hierarchy process (AHP) determined the weights of each indicator. The results showed that the main influencing factors of the water environment for species diversity monitoring were dissolved inorganic nitrogen (DIN) and chemical oxygen demand (COD), and all water quality monitoring items were relatively stable without obvious pollution. The biomass of biological species in the near-shore sea area of Tianjin was relatively low, the species distribution was uneven, and the structure and function of the ecosystem need to be improved since environmental problems still existed.

Spatiotemporal distribution, ecological risk assessment and source analysis of legacy and emerging Per- and Polyfluoroalkyl Substances in the Bohai Bay, China.

The Bohai Sea is one of the most polluted hotspots by per- and Polyfluoroalkyl substances (PFASs) in the world and studies on the vertical distribution of PFASs at different water layers and phase partitioning between water and suspended particulate matter (SPM) were still limited. 23 legacy and emerging PFASs were investigated in seawater and SPM throughout the Bay in this study. The average concentrations of ∑PFASs in seawater were 48.21 ng/L and 52.71 ng/L during the periods of wet and normal water, respectively. In general, the concentrations of ∑PFASs in surface water were higher than that in deep water. Legacy PFASs in seawater were dominated by PFOA and short-chain PFASs, while the emerging alternative HFPO-DA was detected in the whole water layer of the Bohai Bay with an average concentration of 1.09 ng/L. The spatial distribution showed that ∑PFASs were higher nearshore than inside the bay and higher in the south than that in the north of the bay. The average concentration of ∑PFASs in SPM was 9.02 ng/g. Long-chain PFASs and the emerging alternative 6:2 Cl-PFESA accounted for the major contaminants. The partition coefficients log Kd and φspm-w showed a linear positive correlation with carbon chain length. Preliminary risk assessments revealed that the ecological risk of common PFASs in the Bohai Bay was low, while PFOA was at moderate risk. The principal component analysis demonstrated that the production process of traditional fluorochemical factories, fire-fighting and emerging electroplating industries were the main sources of PFASs. This was the first comprehensive survey of emerging PFASs in different water depths and in SPM of the Bohai Bay during different seasons, which provided important scientific data for studying the ecological risks and pollution prevention of PFASs.